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Application

98101589/04, 1998-01-12

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Start date

1998-01-12

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Actual filing date

1998-01-12

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Published

1999-08-27

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Inventor

Dzhemilev U.M.Ibragimov A.G.Khafizova L.O.Deeva E.A.Kunakova R.V.Vasil'Ev Ju.V.Tuktarov R.F.

(73)

Holder

Institut Neftekhimii I Kataliza An Rb

METHOD OF PREPARING 1-(N-PROPYL)-2-HYDRO[6] FULLERENES Russian patent published in 1999 - IPC

Abstract RU 2135446 C1

FIELD: organic synthesis. SUBSTANCE: in order to prepare n-propyl substituted fullerene, toluene solution of (C60) fullerene is reacted with excessive amount of their solution of n-propylmagnesium bromide (n-PrMgBr) or propyl zirconacene dichloride Cp2ZrCl2 in argon atmosphere under normal condition for 8-12 h, and reaction mixture is then treated with aqueous hydrochloric acid, C60 to n-PrMgBr molar ratio is 1:(50-150), catalyst is used in amount of 1-3 mole % with respect to n-PrMgBr. The resulting compounds are used in organic synthesis and as original semiproducts for preparing biologically active substances for medicine and agriculture. EFFECT: more efficient preparation method. 1 ex, 1 tbl

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RU 2 135 446 C1

Authors

Dzhemilev U.M.

Ibragimov A.G.

Khafizova L.O.

Deeva E.A.

Kunakova R.V.

Vasil'Ev Ju.V.

Tuktarov R.F.

Dates

1999-08-27—Published

1998-01-12—Filed

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