FIELD: chemistry of polymers. SUBSTANCE: described catalyst composition for polymerization of olefins comprising metallocene complex on support. Metallocene complex is metallocene complex of general formula I: M[X(R)n]xYp (1) wherein M is metal of group IV A; X is cyclopentadienyl group; R is monovalent C1-C20 hydrocarbon radical of monovalent C1-C20, hydrocarbon radical containing substituting oxygen atoms provided that R is contains functional group of Lewis base; Y is halogen, n is 1, x is 2 and p is 2. Also described are metallocene complex and method of polymerization of olefins. EFFECT: quite active catalyst system with respect to ethylene and alpha-olefins to form polyolefins having narrow molecular weight distribution. 16 cl, 10 ex, 1 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| CATALYST COMPOSITION USED FOR POLYMERIZATION OF OLEFINS | 1993 |
|
RU2165435C2 |
| CATALYST COMPOSITION USED FOR OLEFIN POLYMERIZATION | 1993 |
|
RU2126424C1 |
| TRANSITION METAL COMPLEXES, CATALYST SYSTEM COMPRISING THEREOF, METHOD OF PREPARING POLYOLEFINS, AND POLYOLEFINIC COMPOSITION | 1996 |
|
RU2142953C1 |
| METHOD OF SYNTHESIS OF POLYMER OR ETHYLENE COPOLYMER | 1992 |
|
RU2097388C1 |
| PRELIMINARY POLYMERIZED CATALYTIC COMPOSITION, METHOD FOR ITS PRODUCTION AND METHOD FOR PRODUCTION OF POLYOLEFFINS | 1991 |
|
RU2099358C1 |
| METHOD OF PREPARING POLYMER, METHOD OF PREPARING METALLOCENE, AND DOUBLE- BOUND METALLOCENE | 1996 |
|
RU2165428C2 |
| CATALYST COMPOSITION, METHOD FOR MORPHOLOGY CONTROLLED POLYMERISATION OF OLEFINS AND POLYMER COMPOSITION | 2008 |
|
RU2470945C2 |
| METHOD OF REGULATING COPOLYMER CHAIN STRUCTURE | 2011 |
|
RU2542992C2 |
| POLYMER FILMS | 2007 |
|
RU2489454C2 |
| METHOD OF CONTROLLING BIMODAL CATALYST ACTIVITY DURING POLYMERISATION | 2008 |
|
RU2479593C2 |
