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Application

96110760/04, 1996-05-28

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Start date

1996-05-28

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Actual filing date

1996-05-28

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Published

2000-09-27

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Inventor

Dzhemilev U.M.Ibragimov A.G.Khafizova L.O.Sultanov R.M.Kunakova R.V.Dodonova N.E.

(73)

Holder

Institut Neftekhimii I Kataliza S Opytnym Zavodom An Rb

METHOD OF PREPARING 1-(ALKOXY)-2- PHENYL(ALKYL)ALUMACYCLOPROPANES Russian patent published in 2000 - IPC

Abstract RU 2156769 C2

FIELD: chemical industry. SUBSTANCE: described is method of preparing new 1-(alkoxy)-2-phenyl (alkyl)-alumacyclopropanes of general formula I: wherein R is , which comprises reacting alpha-olefin of formula: with alkoxy- dichloroalanes of formula: RO-AlCl2 and metallic magnesium at molar ratio of 10: (10-14): (10-14), respectively, in the presence of tetraisopropoxytitanium, tetrabutoxytitanium or titanocene dichloride catalyst in amount of 2-6 mole % with respect to alpha-olefin, and reaction is carried out in argon atmosphere under normal conditions in tetrahydrofuran for 6-10 hours. Method makes it possible to prepare new 1-(alkoxy)-2-phenyl (alkyl)alumacyclopropanes of formula I having high regioselectivity. EFFECT: more efficient preparation method. 15 ex, 1 tbl

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RU 2 156 769 C2

Authors

Dzhemilev U.M.

Ibragimov A.G.

Khafizova L.O.

Sultanov R.M.

Kunakova R.V.

Dodonova N.E.

Dates

2000-09-27—Published

1996-05-28—Filed

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