FIELD: components of catalyst systems in processes of oligomerization and polymerization of olefins and diene hydrocarbons, more particularly fine organic and organometal synthesis. SUBSTANCE: method comprises reacting terminal acetylenes of formula: R-≡ wherein R is н-C5H11, н-C6H13, Ph with ethylalumium dichloride and metallic magnesium in the presence of zirconacene dichloride. Reaction is carried out in argon atmosphere under normal conditions for 8-12 hours. Yield of desired products is 62-81%. EFFECT: more efficient preparation method. 2 cl, 12 ex, 1 tbl
Title |
Year |
Author |
Number |
METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)-2,4- DIALKYL(ARYL)ALUMACYCLOPENTADIENES AND 1-(DIALKYL-AMINE)- 2-ALKYL(ARYL)ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Jusupov Z.A.-Ja.
- Khalilov L.M.
- Kunakova R.V.
- Sharipova A.Z.
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METHOD OF COMBINED PREPARATION OF 1-ETHYL-2,3,4,5- TETRAALKYL (ARYL) ALUMACYCLOPENTADIENES AND 1-ETHYL-2,3- DIALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Islamgulova A.Z.
- Kunakova R.V.
- Khalilov L.M.
- Sharipova A.Z.
|
RU2130025C1 |
METHOD OF COMBINED PREPARATION OF 1-(DIALKYLAMINE)- 2,3,4,5-TETRAALKYL (ARYL) ALUMACYCLOPENTADIENES AND 1- (DIALKYLAMINE)-2,3-DIALKYL(ARYL) ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Kunakova R.V.
- Khalilov L.M.
- Islamgulova A.Z.
- Sharipova A.Z.
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METHOD OF COMBINED SYNTHESIS OF 1-(ALKOXY)-2,4-DIALKYL(PHENYL)- -ALUMACYCLOPENTADIENS AND 1-(ALKOXY)-2-ALKYL(PHENYL)ALUMA- -CYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Jusupov Z.A.-Ja.
- Kunakova R.V.
- Khalilov L.M.
- Sharipova A.Z.
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RU2131431C1 |
METHOD OF COMBINED PREPARATION OF 1-(ALKOXY)-2,3,4,5- TETRAALKYL-(ARYL) ALUMACYCLOPENTADIENES AND 1-(ALKOXY)- 2,3-DIALKYL (ARYL)ALUMACYCLOPROPENES |
1997 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Kunakova R.V.
- Khalilov L.M.
- Islamgulova A.Z.
- Sharipova A.Z.
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METHOD OF SYNTHESIS OF 1-ETHYL-2,3-DIPHENYL(ALKYL)ALUMACYCLO-PROPENES |
1996 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Muslukhov R.R.
- Khalilov L.M.
- Ramazanov I.R.
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METHOD OF PREPARING 1-ALKOXY (OR DIALKYLAMINO)-2,3- DIPHENYL(ALKYL)ALUMACYCLOPROPENES |
1996 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Khalimov L.M.
- Muslukhov R.R.
- Sultanov R.M.
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METHOD OF PREPARING 1-CHLORO-2,3- DIPHENYL(ALKYL)ALUMACYCLOPROPENES |
1996 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Khalilov L.M.
- Muslukhov R.R.
- Sultanov R.M.
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METHOD OF COMBINED PREPARATION OF 1-ETHYL-2- PHENYLALUMACYCLOPROPANE AND 1-ETHYL-2,4- DIPHENYLALUMACYCLOPENTANE |
1996 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Khafizova L.O.
- Sultanov R.M.
- Khalilov L.M.
- Rusakov S.V.
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CATALYST FOR SYNTHESIS OF 1-DIALKYLAMINE-2,3-DIPHENYLALUMA- -CYCLOPROPENES |
2000 |
- Dzhemilev U.M.
- Ibragimov A.G.
- Ramazanov I.R.
- Ajsuvakov I.Sh.
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