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Application

96110973/04, 1996-05-30

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Start date

1996-05-30

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Actual filing date

1996-05-30

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Published

2000-09-27

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Inventor

Dzhemilev U.M.Ibragimov A.G.Sultanov R.M.Khafizova L.O.Khalilov L.M.Rusakov S.V.

(73)

Holder

Institut Neftekhimii I Kataliza S Opytnym Zavodom An Rb

METHOD OF COMBINED PREPARATION OF 1-(ALKOXY)-2- PHENYLALUMACYCLOPROPANE AND 1-(ALKOXY)-2,4- DIPHENYLALUMACYCLOPENTANE Russian patent published in 2000 - IPC

Abstract RU 2156772 C2

FIELD: fine organic and organometallic synthesis. SUBSTANCE: described is method of combined preparation of 1-(alkoxy)-2- phenylalumacyclopropane of formula I: and 1-(alkoxy)- 2,4-diphenylalumacyclopentane of formula II: wherein R is n-C6H13,n-C10H21,CH2Ph. Method comprises reacting styrene with alkoxydichloroalanes of general formula: RO-AlCl2 and metallic magnesium at 10:(10-14):(10-14) molar ratio, respectively, in the presence of zirconium tetrachloride catalyst in argon atmosphere in tetrahydrofuran under normal conditions for 6-10 hours. Method makes it possible to prepare both 1-(alkoxy-2- (phenylalumacyclopropane and 1-alkoxy)-2,4- diphenylalumacyclopentane having high regioselectivity. EFFECT: more efficient preparation method. 11 ex, 1 tbl

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RU 2 156 772 C2

Authors

Dzhemilev U.M.

Ibragimov A.G.

Sultanov R.M.

Khafizova L.O.

Khalilov L.M.

Rusakov S.V.

Dates

2000-09-27—Published

1996-05-30—Filed

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