FIELD: chemical industry. SUBSTANCE: described is delignification by electrochemical decomposition of compounds. In this case, both system and method of electrochemical decomposition use mediator in the form of aliphatic, cycloaliphatic, heterocyclic and aromatic compound containing N-oxyfunction and containing no heavy metals, and also electrodes made of steels, precious metals and carbon. EFFECT: simplified process and greater efficiency of lignification. 9 cl, 10 tbl
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