FIELD: polymerization processes. SUBSTANCE: molecular-complex compound consists of (i) mono- or bis-acylphosphine oxide of formula I: (I), in which R1 and R2, independently from each other, denote C1-C12-alkyl, phenyl optionally 1-4-fold substituted by C1-C8-alkyl and/or C1- C8-alkoxyl, or COR3 group; R3 denotes phenyl optionally 1-4-fold substituted by C1-C8-alkyl and/or C1-C8-alkoxyl; and (ii) alpha- hydroxyketone compound of formula II: R11 (II), in which R12 and R11, independently from each other, denote C1-C6- alkyl or R12 and R13, together with carbon atom to which they are linked, form cyclohexyl ring; R14 represents hydroxy; and hydrogen. Proposed compound can be used photoinitiator. Invention also provides photopolymerizing composition, composition for manufacture of varnishes, printing inks, forming plates, dental pastes, resist materials as well as video recording material, in particular for bolographic imaging. EFFECT: extended choice of photopolymerizing materials. 12 cl, 1 tbl, 8 ex
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