Patenton — panteon of patents

(19)

RU

(11)

2 186 067

(13)

C2

(51)

IPC

(21) (22)

Application

2000122179/04, 2000-08-21

(24)

Start date

2000-08-21

(22)

Actual filing date

2000-08-21

(45)

Published

2002-07-27

(72)

Inventor

Dzhemilev U.M.Ibragimov A.G.Khafizova L.O.Gil'Fanova G.N.Prokhorova N.A.Sultanov R.M.

(73)

Holder

Institut Neftekhimii I Kataliza An Rb I Unts Ran

METHOD OF SYNTHESIS OF 1-ETHYL-2-ARYL-METHYLENE-ALUMACYCLOPROPANES Russian patent published in 2002 - IPC

Abstract RU 2186067 C2

FIELD: chemical technology. SUBSTANCE: invention describes a method of synthesis of 1-ethyl-2-aryl-3-methylenealumacyclopropanes of the general formula (1) where Ar is Ph, p-CH3Ph characterized in that arylallenes of the general formula Ar- =•= where Ar is determined above is subjected for interaction with ethylaluminum dichloride (EtAlCl2) and metallic magnesium taken in mole ratio Ar-=•= : (EtAlCl2) : Mg = 10:(10-14): :(10-14), respectively, in the presence of a catalyst (Cp2TiCl2) taken in the amount 2-6 mole % with respect to arylallene in tetrahydrofuran medium. Reaction is performed in argon atmosphere at the room temperature (~20 C) under normal pressure for 6-10 h. The proposed method of synthesis can be used in industrial organic synthesis, in part, in polymerization processes where synthesized compounds take part of cocatalysts. EFFECT: improved method of synthesis. 1 tbl, 10 ex

Similar patents RU2186067C2

Title Year Author Number
METHOD OF COMBINED SYNTHESIS OF 1-ETHYL-2-METHYLENE-3-ALKYL-ALUMACYCLOPROPANES AND 1-ETHYL-1,1-DI-(ALK-1'-ENE-3'-YL)-ALANS 2000
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Prokhorova N.A.
  • Sultanov R.M.
 RU2180665C1
METHOD OF COMBINED PREPARATION OF 1-ETHYL-2-ARYL, 1- ETHYL-3-ARYL, 1-ETHYL-2,4-DIARYL, 1-ETHYL-2,5-DIARYL ALUMACYCLOPENTANES AND 1-ETHYL-2-ARYL ALUMACYCLOPROPANES 1999
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Nikitina E.V.
  • Khalilov L.M.
 RU2157811C1
CATALYST FOR PRODUCTION OF 1-ETHYL-2-ARYLALUMINOCYCLOPROPANES 1999
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Dodonova N.E.
  • Kovtunenko I.A.
  • Sultanov R.M.
 RU2169613C1
CATALYST FOR PREPARING 1-ALKOXY-2-ARYLALUMACYCLOPROPANES 1999
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Satenov K.G.
  • Sultanov R.M.
 RU2176547C2
METHOD OF PREPARING 1-ETHYL-2,3-FULLERENE [60] ALUMACYCLOPROPANES 1999
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Chegodaeva M.F.
  • Tomilov Ju.V.
  • Nefedov O.M.
 RU2160272C1
CATALYST FOR SYNTHESIS OF 1-ETHYL-2-(TRIALKYLXYLYL)-ALUMACYC- LOPROPANES 1999
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Satenov K.G.
  • Gil'Fanova G.N.
  • Sultanov R.M.
 RU2175891C2
METHOD OF SYNTHESIS OF SUBSTITUTED 1-ETHYLALUMO-CYCLOPENTANES 2001
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Kunakova R.V.
  • Sultanov R.M.
 RU2191192C1
METHOD OF COMBINED SYNTHESIS OF 1-ETHYL-2- ALKYLIDENEALUMACYCLOPENTANES AND 1-ETHYL-2- METHYLENE-3- ALKYLALUMACYCLOPENTANES 2000
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Prokhorova N.A.
  • Sultanov R.M.
 RU2183637C2
METHOD OF PREPARING 1-ETHYL-2-(TRIALKYLSILYL) ALUMACYCLOPROPANES 1999
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Satenov K.G.
 RU2162851C2
METHOD FOR PREPARING 1-ETHYL-3-METHYL-3-PHENYL-(ETHYL-, CYCLOPROPYL-)-4-ALKYLIDENECYCLOHEPTA-2-OXALANES 2002
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Sharipova A.Z.
  • Popod'Ko N.R.
 RU2213745C1

RU 2 186 067 C2

Authors

Dzhemilev U.M.

Ibragimov A.G.

Khafizova L.O.

Gil'Fanova G.N.

Prokhorova N.A.

Sultanov R.M.

Dates

2002-07-27—Published

2000-08-21—Filed

read Similar patents