FIELD: polymer production.
SUBSTANCE: invention provides homogenous catalytic system for synthesis of copolymers and terpolymers of olefinic monomers, which system contains dialkyl bridge-type bis(indenyl)metallocene complexes with group IVB metals and trialkylaluminum at Al-to-metal ratio between 50 and 500. Catalytic system enables carrying out polymerization process at rates significantly exceeding ethylene or propylene homopolymerization rate.
EFFECT: significantly accelerated copolymerization process and achieved fractional and compositional homogeneity of ethylene/α-olefin and propylene/α-olefin copolymers.
1 tbl, 16 ex
Title |
Year |
Author |
Number |
METHOD OF PRODUCING COPOLYMERS OF OLEFIN MONOMERS WITH CYCLIC OR LINEAR DIENES |
2011 |
- Bravaja Natal'Ja Mikhajlovna
- Panin Andrej Nikolaevich
|
RU2477289C1 |
USE OF ARYL OXIDES OF ISOBUTYL ALUMINIUM AS ACTIVATORS DIALKYL METALLOCENE CATALYSTS FOR HOMOPOLYMERISATION ETHYLENE, PROPYLENE, COPOLYMERISATION OF ETHYLENE WITH PROPYLENE AND TRIPLE COPOLYMERISATION OF ETHYLENE, PROPYLENE AND DIENE, HOMOGENEOUS METALLOCENE CATALYST SYSTEMS FOR SYNTHESIS OF HOMO-AND COPOLYMERS OF OLEFINS AND DIENES, METHOD OF PRODUCING HOMO- AND COPOLYMERS OF OLEFINS AND DIENES, METHOD FOR STABILISATION OF HOMO- AND COPOLYMERS OF OLEFINS AND DIENES |
2014 |
- Fajngold Evgenij Efimovich
- Bravaya Natalya Mikhajlovna
- Panin Andrej Nikolaevich
- Saratovskikh Stanislav Lvovich
- Babkina Olga Nikolaevna
|
RU2588496C2 |
CATALYST(S) FOR COPOLYMERIZATION OF OLEFINS, METHOD OF PREPARING OLEFIN HOMO OR COPOLYMERS |
1993 |
- Luidzhi Reskoni
- Mauritsio Galimberti
- Fabritsio P'Emontesi
- Floriano Gal'El'Mi
- Ehnriko Al'Bitstsati
|
RU2132229C1 |
VANADIUM CATALYST SYSTEM FOR COPOLYMERISATION OF ETHYLENE WITH ALPHA-OLEFINS (VERSIONS) AND METHOD OF PRODUCING ETHYLENE AND ALPHA-OLEFIN COPOLYMER (VERSIONS) |
2010 |
- Kochnev Andrej Ivanovich
- Maksimov Denis Aleksandrovich
- Ashirov Roman Vital'Evich
- Smirnova Ol'Ga Valentinovna
|
RU2505549C2 |
IMMOBILIZED CATALYST FOR MONO-AND COPOLYMERIZATION OF OLEFINS, METHOD OF PREPARING THEREOF AND METHOD OF PREPARING HOMO-AND COPOLYMERS OF OLEFINS |
1999 |
- Bravaja N.M.
- Chukanova O.M.
- Saratovskikh S.L.
- Babkina O.N.
- Panin A.N.
|
RU2171814C1 |
ETHYLENE-PROPYLENE COPOLYMER, ELASTOMERIC COPOLYMER, MOLDED PRODUCT, AND METHOD OF PREPARING COPOLYMER |
1994 |
- Mauritsio Galimberti
- Luidzhi Reskoni
- Ehnriko Al'Bidzati
|
RU2140426C1 |
ETHYLENE COPOLYMERS AND THEIR PRODUCTS |
1993 |
- Mauritsio Galimberti
- Luidzhi Reskoni
- Ehmilio Martini
- Floriano Gul'El'Mi
- Ehnriko Al'Bitstsati
|
RU2114868C1 |
ELASTOMERIC ETHYLENE POLYMERS AND METHOD OF PREPARING THEREOF |
1994 |
- Mauritsio Galimberti
- Ehnriko Al'Bitstsati
|
RU2143441C1 |
PRODUCTION METHOD OF PROPYLENE BLOCK-COPOLYMER |
2015 |
- Imai Masafumi
- Sugano Tosikhiko
- Uodzumi Tosiya
- Khaga Yuta
|
RU2692484C2 |
ETHYLENE-OLEFIN MONOMER COPOLYMER, METHOD OF PREPARING THEREOF, AND CATALYST |
1993 |
- Luidzhi Ressoni
- Titsiano Dall''Okko
- Fabritsio P'Emontezi
- Floriano Gul'El'Mi
- Ehnriko Al'Bitstsati
|
RU2140930C1 |