FIELD: petrochemical processes.
SUBSTANCE: propylene is subjected to oligomerization in presence of phosphoric acid catalyst at elevated temperature and pressure. Propylene dimer fraction is separated from oligomerizate and returned into oligomerization process simultaneously normal α-olefin fraction and fraction containing C6 and C8-olefins. Weight ratio of the two fraction is (4-1):(1-4), respectively.
EFFECT: increased yield of propylene trimers and tetramers and enabled controlling proportions and yields thereof.
3 cl, 1 tbl, 6 ex
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Authors
Dates
2005-06-27—Published
2004-03-18—Filed