FIELD: hydrometallurgy of noble metals.
SUBSTANCE: the invention is pertaining to the field of hydrometallurgy of noble metals, in particular, to the methods of extraction of gold and silver from various kinds of polymetallic raw materials, composition of which may include copper, nickel, stannum, lead, noncorrosive steel and other metals. The technical result ensures a selective extraction of gold and silver from the current-conducting materials ensuring the high speeds of dissolution of precious metals. The method provides for a treatment of a material placed in the anodic chamber of an electrolyzer and acting as an anode with an acid solution of thiourea (25-100 g/l, pH = 0.5-2.0), passing of a direct current flow and realization of an electrolysis at the temperature of 20-35°C in a controlled potential mode at potential of the anode = +0.380 ÷ +0.420V in respect to a normal hydrogen electrode. The speed of the gold dissolution reaches 0.43 mg/cm2 per a minute, silver - 0.37 mg/cm2 per a minute. The degree of extraction of gold makes 99.9 %, silver - 99.6 %.
EFFECT: the invention ensures a selective extraction of gold and silver from the current-conducting materials at high speeds of dissolution of precious metals.
3 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF ELECTROCHEMICAL EXTRACTION OF SILVER FROM SILVER-BEARING CURRENT-CONDUCTING WASTES | 2011 |
|
RU2467082C1 |
METHOD OF SILVER EXTRACTION FROM SILVER-CONTAINING ALLOY | 2013 |
|
RU2540242C1 |
METHOD OF EXTRACTING GOLD AND SILVER FROM THIOCARBAMIDE SOLUTIONS BY ELECTROLYSIS | 0 |
|
SU770274A1 |
PROCEDURE FOR PRODUCTION OF HIGH AND NANO DISPERSED POWDER OF METALS OR ALLOYS | 2009 |
|
RU2423557C2 |
METHOD OF EXTRACTION OF SILVER FROM THE ACID SOLUTION OF SILVER NITRATE BY METHOD OF ELECTROWINNING | 2017 |
|
RU2650372C1 |
METHOD OF EXTRACTING OF NOBLE METALS FROM WASTES OF RADIOELECTRONIC INDUSTRY | 2014 |
|
RU2553320C1 |
METHOD OF LEACHING-OUT POLYMETALLIC RAW MATERIAL AND DEVICE FOR REALIZATION OF THIS METHOD | 2003 |
|
RU2245378C1 |
METHOD FOR EXTRACTING GOLD FROM GOLD CONTAINING POLYMETALLIC MATERIALS | 2000 |
|
RU2181780C2 |
METHOD FOR PROCESSING POLYMETALLIC RAW MATERIALS (VARIANTS) AND DEVICE FOR ITS LEACHING | 2016 |
|
RU2655413C9 |
METHOD OF EXTRACTION OF METALS | 2006 |
|
RU2312909C1 |
Authors
Dates
2005-08-20—Published
2004-03-17—Filed