FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for preparing polyamide that can be used as a structural material. Polyamide is prepared by co-polymerization reaction of ε-caprolactam and 1,6-hexamethylenediisocyanate taken among the group of di-isocyanates or urethane prepolymer SKU-PFL-100 in the mass ratio = (95-90):(5-10) in the presence of catalyst and activating agent. As a catalyst method involves using ε-caprolactam Na-salts and 2,4-toluylenedi-isocyanate as an activating agent. The process is carried out at temperature (180 ± 5)°C up to depletion of lactam cycles followed by heating the reaction mass for 2 h. Invention provides preparing polyamides with enhanced values of destroying stress (breaking point) and to expand assortment of methods providing preparing polyamides with different physical-mechanical properties.
EFFECT: improved preparing method.
2 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR POLYAMIDE PRODUCTION | 2004 |
|
RU2258072C1 |
METHOD FOR PREPARING POLYAMIDE | 2004 |
|
RU2260015C1 |
POLYAMIDE PRODUCTION PROCESS | 2001 |
|
RU2218360C2 |
ADHESIVE PRODUCTION METHOD | 2001 |
|
RU2218377C2 |
POLYMERIC COMPOSITION | 2002 |
|
RU2233297C1 |
POLYURETHANE COMPOSITION | 2004 |
|
RU2280048C1 |
POLYMERIC COMPOSITION | 2000 |
|
RU2177012C1 |
METHODS OF PRODUCING CAST POLYAMIDES, STABLE DURING STORAGE OF MIXTURES OF ACTIVATORS AND CATALYSTS, AS WELL AS USE THEREOF TO PRODUCE CAST POLYAMIDES | 2011 |
|
RU2596880C2 |
MOULDED POLYAMIDES, METHOD OF THEIR PRODUCTION AND THEIR APPLICATION | 2013 |
|
RU2631324C2 |
METHOD FOR PRODUCTION OF POLYAMIDE BY ANIONIC POLYMERIZATION OF CAPROLACTAM | 1992 |
|
RU2074866C1 |
Authors
Dates
2005-09-10—Published
2004-03-22—Filed