FIELD: chemical technology, in particular production of formaldehyde derivatives.
SUBSTANCE: disclosed is continuous method for methylal production from aqueous solutions of formaldehyde and methanol in presence of tungstic heteropolyacid (silicotungstic and phosphotungstic acids) catalyst in rectifier reactor, wherein simultaneously chemical reaction is carried out and product is rectified or distilled from reaction zone. Further catalyst (heteropolyacid) is isolated from slop by water vaporization and recycled.
EFFECT: environmentally friendly method with decreased cost and energy consumption.
2 ex, 1 dwg
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Authors
Dates
2005-10-10—Published
2004-05-12—Filed