FIELD: polymer production.
SUBSTANCE: siloxane-containing polyamides with molecular weight 58200-460000 are quantitatively obtained by single-step polycondensation of aromatic tetracarboxylic acid anhydrides with siloxane-containing diamines in supercritical carbon dioxide medium at 130-180°C and pressure 32.5 MPa.
EFFECT: enabled process accomplished in a neutral nontoxic medium and simplified process flowsheet.
8 ex
Title | Year | Author | Number |
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Authors
Dates
2006-02-27—Published
2005-02-02—Filed