FIELD: chemistry of polymers, chemical technology.
SUBSTANCE: invention relates to a field for preparing elastic phosphorus-boron-containing polyurethans. Invention describes a method for preparing phosphorus-boron-containing polyurethane by interaction of prepolymer prepared by interaction of hydroxyl-containing compound with di-isocyanate in the mole ratio OH : NCO-groups = 1:2 with phosphorus-boron-containing polyol of the formula (I): (see appendix I) wherein R means -CH2-CH2-; -CH2-CH2-O-CH2-CH-; -CH2-CH(OH)-CH2-; -CH2-CH2-CH2-CH2-. Reaction is carried out in dimethylformamide medium in the mole ratio of prepolymer and phosphorus-boron-containing polyol = 1:(0.1-1). Proposed invention provides preparing elastic self-extinguishing phosphorus-boron-containing polyurethans with tear resistance value at the level 58 MPa and strength value 62.3 MPa. Proposed materials can be used as glues, lacquers, structural materials with reduced inflammability and high physical-mechanical properties.
EFFECT: improved preparing method, improved and valuable properties of materials.
2 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
PHOSPHORUS-BORON-CONTAINING POLYOLS AS INFLAMMATION INHIBITORS FOR POLYURETHANE-BASED ELASTOMER MATERIALS | 2004 |
|
RU2270206C1 |
SIMULATED LEATHER | 2006 |
|
RU2307208C1 |
POLYURETHANE COATING COMPOSITION | 2008 |
|
RU2391362C2 |
TEXTILE MATERIALS TREATMENT PROCESS | 2006 |
|
RU2307207C1 |
POLYURETHANE COATING COMPOSITION | 2019 |
|
RU2715541C1 |
METHOD OF PRODUCING HEAT-RESISTANT LEATHER | 2017 |
|
RU2647912C1 |
0 |
|
SU560892A1 | |
ARTIFICIAL SKIN | 1998 |
|
RU2142030C1 |
PHOSPHORUS-BORON-CONTAINING METHACRYLATE AS POLYVINYL ALCOHOL-BASE FILM MATERIAL COMBUSTION INHIBITOR | 2003 |
|
RU2254327C1 |
METHOD FOR COMBINED PRODUCTION OF FLUORINE-CONTAINING PREPOLYMERS | 2012 |
|
RU2479598C1 |
Authors
Dates
2006-04-27—Published
2004-07-06—Filed