FIELD: petroleum chemistry.
SUBSTANCE: 1,3-butadiene is exposed to telomerization with telogene of general formula H-X-Y-H, wherein X represents oxygen, sulfur, nitrogen or phosphorus; Y represents carbon, nitrogen or silicium; and X and Y optionally may have substituents according to valence thereof to form telomer of general formula H2C=CH-CH2-CH2-CH2-CH=CH-CH2-X-Y-H. Said telomer is hydrolyzed to 1-substituted 2-octene of formula H3C-CH-CH2-CH2-CH2-CH=CH-CH2-X-Y-H. Substituted 2-octene is splitted to produce 1-octene.
EFFECT: improved method for production of 1-octene.
28 cl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF TELOMERIZATION OF DIENE WITH CONJUGATED DOUBLE BONDS, CATALYST AND BIDENTATE LIGAND USED IN INDICATED METHOD | 2002 |
|
RU2318790C2 |
METHOD OF PRODUCING 1-BUTENE AND 1,3-BUTADIENE DERIVATIVE | 2012 |
|
RU2585764C2 |
METHOD OF PRODUCING DIANES VIA HYDRODIMERISATION | 2007 |
|
RU2421440C2 |
METHOD OF PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL | 1995 |
|
RU2135456C1 |
CATALYTIC COMPOSITION FOR HYDROGENATION OF OLEFINICALLY UNSATURATED COMPOUNDS, METHOD OF PREPARATION THEREOF, AND METHOD OF HYDROGENATION OF OLEFINICALLY UNSATURATED COMPOUNDS | 1998 |
|
RU2162472C2 |
THIOESTERIFICATION OF MERCAPTANES IN MIXTURES OF HYDROCARBONS C4 | 2013 |
|
RU2628085C2 |
METHOD OF HYDROPHOMYLATION OF OLEFINE COMPOUNDS IN PRESENCE OF CYCLIC ETHERS OF CARBONIC ACID | 2003 |
|
RU2337090C2 |
METHOD OF SYNTHESIS OF OCTA-2,7-DIENE-1-OL | 1993 |
|
RU2120432C1 |
DIPHOSPHINE AND METAL COMPLEXES | 2006 |
|
RU2408600C2 |
TRANSITION METAL AND PHOSPHINE-BASED CATALYST PREPARATION METHOD | 1996 |
|
RU2167712C2 |
Authors
Dates
2006-07-10—Published
2002-01-18—Filed