METHOD FOR PRODUCTION OF 3,6-DIMETHYL-1,8-DIALKYL(PHENYL)-2,6-OCTADIENS Russian patent published in 2006 - IPC C07C11/12 

Abstract RU 2283826 C1

FIELD: organic chemistry.

SUBSTANCE: alkyl(benzyl)allene of general formula (R-= =), wherein R is n-C2H11, n-C6H13,CH2Ph is reacts with EtMgBr, Mg, Cp2TiCl2, methyl iodide and CuCl in argon atmosphere in tetrahydrofuran medium for 18-22 hours. Total yield of target products is 69-86 %.

EFFECT: selective method for production of 3,6-dimethyl-4,7-dialkyl(phenyl)-2,6-octadiens.

1 tbl, 1 ex

Similar patents RU2283826C1

Title Year Author Number
METHOD FOR PREPARING 4,7-DIALKYL(BENZYL)IDENE-2,10-DODECADIENES 2005
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • D'Jakonov Vladimir Anatol'Evich
  • Khalilov Leonard Mukhibovich
  • Kunakova Rajkhana Valliulovna
  • Ushakova Zoja Ivanovna
RU2286328C1
METHOD FOR PRODUCTION OF 2,9-DIMETHYL-4,7-DIALKYL(BENZYL)IDEN-1,9-DECADIENS 2005
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • D'Jakonov Vladimir Anatol'Evich
  • Prokhorova Natal'Ja Anatol'Evna
  • Kunakova Rajkhana Valiullovna
  • Sharipova Al'Fija Zufarovna
RU2283828C1
METHOD FOR PRODUCTION OF 4,7-DIALKYL(BENZYL)IDEN-1,9-DECADIENS 2005
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • D'Jakonov Vladimir Anatol'Evich
  • Prokhorova Natal'Ja Anatol'Evna
  • Khalilov Leonard Mukhibovich
  • Tjumkina Tat'Jana Viktorovna
RU2283827C1
METHOD FOR PREPARING 1,6-DIALKYL-2,5-BIS-(ETHYLMAGNESA)-1,5-HEXADIENES 2003
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • D'Jakonov V.A.
  • Majstrenko V.V.
  • Prokhorova N.A.
RU2238942C1
METHOD FOR PREPARING 1,6-DIALKYL(BENZYL)-2,5-DIPHENYL-1,5-HEXADIENES 2005
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • D'Jakonov Vladimir Anatol'Evich
  • Popod'Ko Natal'Ja Romanovna
  • Salamatina Tat'Jana Petrovna
  • Golikova Majja Timofeevna
RU2283296C1
METHOD OF PRODUCING 2,3-DIALKYL-5-ALKYLIDENEMAGNESA-CYCLOPENT-2-ENES 2006
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • D'Jakonov Vladimir Anatol'Evich
  • Zinnurova Regina Adikovna
  • Sharipova Al'Fija Zufarovna
  • Tjumkina Tat'Jana Viktorovna
RU2374255C2
METHOD OF SYNTHESIS OF 1,3-DIALKYL-2-(N-PROPYL)-PROP-2Z-EN-1-OLS 2001
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Jalalova D.F.
  • Kunakova R.V.
  • Prokhorova N.A.
RU2200146C1
METHOD FOR PREPARING 2,3-DIALKYL-5-ALKYLIDENEMAGNESACYCLOPENT-2-ENES 2005
  • Dzhemilev Usein Memetovich
  • Ibragimov Askhat Gabdrakhmanovich
  • D'Jakonov Vladimir Anatol'Evich
  • Zinnurova Regina Adikovna
  • Dzhemileva Galina Arkad'Evna
  • Khalilov Leonard Mukhibovich
RU2291870C1
METHOD OF PRODUCING 1,2-DIALKYLBORINANES 2017
  • Khafizova Lejla Osmanovna
  • Khusainova Liliya Inverovna
  • Ryazanov Kirill Sergeevich
  • Tyumkina Tatyana Viktorovna
  • Dzhemilev Usein Memetovich
RU2688195C2
METHOD FOR PREPARING 1-ETHYL-3-METHYL-3-PHENYL-(ETHYL-, CYCLOPROPYL-)-4-ALKYLIDENECYCLOHEPTA-2-OXALANES 2002
  • Dzhemilev U.M.
  • Ibragimov A.G.
  • Khafizova L.O.
  • Gil'Fanova G.N.
  • Sharipova A.Z.
  • Popod'Ko N.R.
RU2213745C1

RU 2 283 826 C1

Authors

Dzhemilev Usein Memetovich

Ibragimov Askhat Gabdrakhmanovich

D'Jakonov Vladimir Anatol'Evich

Popod'Ko Natal'Ja Romanovna

Dodonova Nina Egorovna

Kovtunenko Irina Anatol'Evna

Dates

2006-09-20Published

2005-05-13Filed