FIELD: organic chemistry.
SUBSTANCE: alkyl(benzyl)allene of general formula (R-= =), wherein R is n-C2H11, n-C6H13,CH2Ph is reacts with EtMgBr, Mg, Cp2TiCl2, methyl iodide and CuCl in argon atmosphere in tetrahydrofuran medium for 18-22 hours. Total yield of target products is 69-86 %.
EFFECT: selective method for production of 3,6-dimethyl-4,7-dialkyl(phenyl)-2,6-octadiens.
1 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING 4,7-DIALKYL(BENZYL)IDENE-2,10-DODECADIENES | 2005 |
|
RU2286328C1 |
METHOD FOR PRODUCTION OF 2,9-DIMETHYL-4,7-DIALKYL(BENZYL)IDEN-1,9-DECADIENS | 2005 |
|
RU2283828C1 |
METHOD FOR PRODUCTION OF 4,7-DIALKYL(BENZYL)IDEN-1,9-DECADIENS | 2005 |
|
RU2283827C1 |
METHOD FOR PREPARING 1,6-DIALKYL-2,5-BIS-(ETHYLMAGNESA)-1,5-HEXADIENES | 2003 |
|
RU2238942C1 |
METHOD FOR PREPARING 1,6-DIALKYL(BENZYL)-2,5-DIPHENYL-1,5-HEXADIENES | 2005 |
|
RU2283296C1 |
METHOD OF PRODUCING 2,3-DIALKYL-5-ALKYLIDENEMAGNESA-CYCLOPENT-2-ENES | 2006 |
|
RU2374255C2 |
METHOD OF SYNTHESIS OF 1,3-DIALKYL-2-(N-PROPYL)-PROP-2Z-EN-1-OLS | 2001 |
|
RU2200146C1 |
METHOD FOR PREPARING 2,3-DIALKYL-5-ALKYLIDENEMAGNESACYCLOPENT-2-ENES | 2005 |
|
RU2291870C1 |
METHOD OF PRODUCING 1,2-DIALKYLBORINANES | 2017 |
|
RU2688195C2 |
METHOD FOR PREPARING 1-ETHYL-3-METHYL-3-PHENYL-(ETHYL-, CYCLOPROPYL-)-4-ALKYLIDENECYCLOHEPTA-2-OXALANES | 2002 |
|
RU2213745C1 |
Authors
Dates
2006-09-20—Published
2005-05-13—Filed