FIELD: rubber industry.
SUBSTANCE: invention relates to process of manufacturing synthetic rubber, in particular solution butadiene-styrene rubber suitable in manufacture of tires with high performance characteristics, resistance to high wheel rolling and providing long lifetime, good maneuverability, adhesion to wet pavement, and low consumption of fuel. Butadiene-styrene rubber is obtained via copolymerization of butadiene with styrene in hydrocarbon solvent and in presence of organolithium catalyst and modifying additive at catalyst-to-additive molar ratio 1:(0.2-1.0). Process comprises mixing monomers with solvent, deactivation of catalyst to stabilize polymer, degassing, and drying of rubber. As modifying additive, alkali metal alcoholates originated from hydroxyalkylated secondary amines.
EFFECT: enabled manufacture of butadiene-styrene rubber with middle and predominant content of 1,2-units in butadiene portion of copolymer.
2 tbl, 22 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PREPARING BUTADIENE-STYRENE RUBBER | 2001 |
|
RU2206581C2 |
POLYMER COMPOSITION AND METHOD FOR ITS PREPARATION | 2018 |
|
RU2779762C1 |
METHOD FOR OBTAINING RANDOMIZED COPOLYMERS WITH A LOW CONTENT OF VINYL GROUPS, COPOLYMERS OBTAINED BY THIS METHOD, AND RUBBER MIXTURES BASED ON THESE COPOLYMERS | 2018 |
|
RU2762602C1 |
METHOD OF PRODUCING BUTADIENE-STYRENE STATISTICAL POLYMERS | 2010 |
|
RU2434025C1 |
METHOD OF OBTAINING FUNCTIONALISED POLYMERS OF BUTADIENE AND COPOLYMERS OF BUTADIENE WITH STYRENE | 2013 |
|
RU2538591C1 |
METHOD OF PRODUCING BUTADIENE POLYMERS AND COPOLYMERS OF BUTADIENE WITH STYRENE | 2008 |
|
RU2377258C2 |
METHOD OF PRODUCING MODIFYING ADDITIVE OF ORGANOLITHIUM COMPOUND AND METHOD OF PRODUCING POLYBUTADIENE AND COPOLYMERS OF BUTADIENE WITH STYRENE | 2008 |
|
RU2382792C2 |
METHOD FOR OBTAINING BUTADIENE-STYRENE RUBBERS | 2007 |
|
RU2339652C1 |
BUTADIENE POLYMERS' AND BUTADIENE/STYRENE COPOLYMERS' PRODUCTION PROCESS | 2003 |
|
RU2228339C1 |
METHOD OF OBTAINING BLOCK-COPOLYMERS | 2014 |
|
RU2554341C1 |
Authors
Dates
2006-10-20—Published
2005-06-06—Filed