FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for synthesis of sulfonyl chlorides. Method involves oxidation of thiol of the formula: R-SH wherein R means (C1-C20)-alkyl, benzyl, methylphenyl or disulfide of the formula: R-SS-R wherein R means (C1-C20)-alkyl with chlorine dioxide in organic solvent medium in the mole ratio thiol or disulfide to chlorine dioxide = 1:(2-4), respectively, at temperature 10-30°C. Also, invention describes preferable conditions for carrying out the process. Using chlorine dioxide provides enhancing the effectiveness of method. Proposed compounds can be used in manufacturing detergents, ion-exchange resins, elastomers, medicinal agents, dyes, herbicides, as an intermediate products in synthesis of sulfoacid esters, and as mild alkylating agents used in organic synthesis.
EFFECT: improved method of synthesis.
7 cl, 11 ex
| Title | Year | Author | Number |
|---|---|---|---|
| THIOLSULFONATE PRODUCTION PROCESS | 2006 |
|
RU2302407C1 |
| SULPHO-DERIVATIVES BASED ON BETA-PINENE AND A METHOD FOR PRODUCTION THEREOF | 2019 |
|
RU2708617C1 |
| CHIRAL Γ-KETOSULPHONYL DERIVATIVES OF THE PINANE STRUCTURE AND METHOD FOR PRODUCTION THEREOF | 2021 |
|
RU2780452C1 |
| CHOLESTEROL SULPHOCHLORIDE AND A METHOD FOR PRODUCTION THEREOF | 2019 |
|
RU2695361C1 |
| CHIRAL 18-SULPHO-DERIVATIVES OF DEHYDROABIETANE AND A METHOD FOR PRODUCTION THEREOF | 2020 |
|
RU2726793C1 |
| METHOD OF PRODUCING DIMETHYL SULPHOXIDE | 2010 |
|
RU2440336C1 |
| METHOD FOR PRODUCING MONOTERPENE SULFONIC ACID | 2016 |
|
RU2651791C2 |
| CHIRAL γ-KETOSULFANYL DERIVATIVES OF PINANE STRUCTURE AND THEIR PRODUCTION METHOD | 2021 |
|
RU2783164C1 |
| HYBRID THREE-DIMENSIONAL SULFUR CO-POLYMERS COMPRISING CONDUCTING AND NON-CONDUCTING POLYMERIC BLOCKS AND THEIR COMPOSITIONS WITH SULFUR USED AS CATHODE MATERIALS | 2004 |
|
RU2275392C1 |
| METHOD OF PRODUCING 2,6-DIISOBORNYLBENZOQUINONE | 2011 |
|
RU2457196C1 |
