FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention relates to a method for oxidizing liquid hydrocarbons in barrier discharge carried out in the bubble reactor with mixtures of oxygen with helium, argon or nitrogen. Method involves using helium, argon and nitrogen taken in the amount 20-80%. The oxidation process is carried out in the presence of solid additives wherein aluminum, nickel, molybdenum, copper oxides or zeolite catalyst ZSM-5 comprising 1.2% of Fe is used. Method provides reducing energy consumptions for oxidation of the parent hydrocarbon in the barrier discharge.
EFFECT: improved oxidizing method.
3 cl, 2 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING HYDROCARBONS OF ISOMERIC STRUCTURE | 1997 |
|
RU2123992C1 |
METHOD OF PROCESSING ORGANIC MATERIAL (VERSIONS) | 2011 |
|
RU2458966C1 |
METHOD FOR PREPARATION OF COPPER-CONTAINING ZEOLITES AND USE THEREOF | 2020 |
|
RU2736265C1 |
METHOD FOR COMPLEX PROCESSING OF GASEOUS CARBON-CONTAINING MATERIAL (VERSIONS) | 2011 |
|
RU2473663C2 |
METHOD OF SCRUBBING THE EXHAUST GASES FROM NITROGEN OXIDES | 1995 |
|
RU2088316C1 |
METHOD AND APPARATUS FOR PARTIAL OXIDATION OF LOWER HYDROCARBONS IN ELECTRIC DISCHARGE | 1995 |
|
RU2088565C1 |
HIGH-OCTANE GASOLINE FRACTION AND AROMATIC HYDROCARBON PRODUCTION PROCESS | 2001 |
|
RU2186089C1 |
METHOD OF PRODUCING LOWER OLEFINS | 1994 |
|
RU2074230C1 |
METHOD OF ACTIVATION OF ZEOLITE CATALYSTS FOR PROCESS OF OXIDIZING HYDROXYLATION OR AROMATIC COMPOUNDS | 2001 |
|
RU2192308C1 |
BENZENE-BASED CYCLOHEXANONE PRODUCTION PROCESS | 2002 |
|
RU2205819C1 |
Authors
Dates
2007-02-10—Published
2004-12-03—Filed