FIELD: industrial organic synthesis.
SUBSTANCE: process is accomplished via catalytic chlorination of acetic acid at elevated temperature involving as catalyst crude acetyl chloride obtained as by-product in oxyethylidenediphosphonic acid synthesis at acetic acid-to-crude acetyl chloride weight ratio 1:(0.1-0.4). Crude acetyl chloride is employed either individually or in the form of acetic acid solution with content of principal solution no less than 90 wt %.
EFFECT: reduced level of dichloroacetic acid in final product and enabled utilization of chemical production waste.
2 cl, 6 ex
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Authors
Dates
2007-07-10—Published
2005-10-27—Filed