FIELD: electrical engineering; manufacture of tubular cells for batteries of high-temperature electrochemical devices.
SUBSTANCE: intermediate layer of micron particles is formed in each electrode-electrolyte interface to enlarge effective surface area of microrelief solid electrolyte. Solid-oxide cell can be made with supporting electrolyte, 100 =- 150 μm thick, with one of electrolytes, with one supporting electrode, or with both supporting electrodes. Proposed method for manufacturing tubular cells includes production of tubular-cell multilayer structures with different alternatives of microrelief, and with layers differing in microstructure using film-forming technology, for instance with micron and nanometric-size high-temperature ceramic powder based polyvinyl butyral drosses, followed by joint molding and sintering of all tubular-cell components.
EFFECT: enhanced strength, heat-resistance, and gas-tightness, enlarged effective surface area of electrode-to-electrolyte interface.
9 cl, 6 dwg
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Authors
Dates
2007-11-10—Published
2005-12-16—Filed