METHOD FOR PREPARING HIGHER SATURATED CHLORINATED ACIDS Russian patent published in 2007 - IPC C07C53/19 C07C51/215 C07C51/225 

Abstract RU 2312098 C1

FIELD: chemistry of halogenated hydrocarbon, chemical technology.

SUBSTANCE: invention relates to an improved method for synthesis of higher saturated chlorinated acids of the general formula: R(CHCl)nCOOH wherein R means aliphatic hydrocarbon radical comprising 9-22 carbon atoms; n = 1-4. Method involves oxidation of chloroparaffins in the presence of catalyst that is mixed with chloroparaffins in the presence of air oxygen at temperature 120-1250C, and oxidation is carried out with air oxygen at temperature 105-1100C under atmosphere pressure for 30-32 h, and wherein cobalt stearate is used as catalyst taken in the amount 1.5-1.7 wt.-% of the reaction mass. Invention provides increasing rate in carrying out the reaction and simplifying the method.

EFFECT: improved method of synthesis.

5 ex

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RU 2 312 098 C1

Authors

Zotov Jurij L'Vovich

Butakova Natal'Ja Aleksandrovna

Korol'Kov Oleg Vladimirovich

Danilov Nikolaj Petrovich

Dates

2007-12-10Published

2006-09-20Filed