FIELD: chemistry of halogenated hydrocarbon, chemical technology.
SUBSTANCE: invention relates to an improved method for synthesis of higher saturated chlorinated acids of the general formula: R(CHCl)nCOOH wherein R means aliphatic hydrocarbon radical comprising 9-22 carbon atoms; n = 1-4. Method involves oxidation of chloroparaffins in the presence of catalyst that is mixed with chloroparaffins in the presence of air oxygen at temperature 120-1250C, and oxidation is carried out with air oxygen at temperature 105-1100C under atmosphere pressure for 30-32 h, and wherein cobalt stearate is used as catalyst taken in the amount 1.5-1.7 wt.-% of the reaction mass. Invention provides increasing rate in carrying out the reaction and simplifying the method.
EFFECT: improved method of synthesis.
5 ex
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METHOD FOR PREPARING HIGHER SATURATED CHLORINATED ACIDS | 2002 |
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POLYMERIC COMPOSITION FOR ARTICLES | 2007 |
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POLYMERIC COMPOSITION FOR ARTICLES | 2006 |
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RU2295549C1 |
METHOD OF PREPARING ALIPHATIC ACIDS | 0 |
|
SU727620A1 |
METHOD OF PARAFFIN OXIDATION | 0 |
|
SU1142467A1 |
METHOD OF SYNTHETIC ACID PRODUCTION | 0 |
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SU789497A1 |
METHOD OF PRODUCING SYNTHETIC ALIPHATIC ACIDS | 0 |
|
SU804629A1 |
Authors
Dates
2007-12-10—Published
2006-09-20—Filed