FIELD: chemical technology.
SUBSTANCE: invention relates to a method for synthesis of tetrachloroethylene from organochlorine (C1-C2)-waste and recurrent tetrachloromethane by gas-phase conversion at temperature 450-6000C in the presence chlorine acceptor and chlorine excess in reaction gases 10-15 wt.-%. The process of gas-phase conversion is combined with exothermic reaction of exhausting chlorination of methane and/or chloromethane. Invention provides the autothermal process for utilization of liquid and gaseous organochlorine waste in manufacturing chloromethanes by combining with exothermic reaction of exhausting chlorination of methane and/or chloromethane resulting to preparing tetrachloroethylene as the end product and decreasing formation of high-boiling by-side organochlorine substances.
EFFECT: improved method of synthesis.
1 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF NEUTRALISING AND DRYING REACTION GASES FROM CHLOROMETHANE PRODUCTION | 2014 |
|
RU2559882C1 |
METHOD OF RECYCLING CHLORORGANIC WASTES | 2013 |
|
RU2560773C2 |
METHOD OF PRODUCING CHLOROMETHANES | 2007 |
|
RU2358961C1 |
METHOD OF SYNTHESIS OF CHLOROFORM | 1999 |
|
RU2165917C1 |
METHOD FOR TREATMENT OF ORGANOCHLORINE MANUFACTURE WASTE FROM RESINIFICATION PRODUCTS | 2006 |
|
RU2313513C1 |
COMPOUND METHOD FOR CATALYTIC PROCESSING OF NATURAL GAS TO OBTAIN LOWER OLEFINS | 2011 |
|
RU2451005C1 |
METHOD OF PRODUCING TETRACHLOROETHYLENE | 2010 |
|
RU2434837C1 |
CATALYTIC METHOD OF PROCESSING METHANE | 2008 |
|
RU2394805C2 |
0 |
|
SU388529A1 | |
METHOD OF PRODUCTION OF THE CHLOROFORM | 2006 |
|
RU2316534C1 |
Authors
Dates
2007-12-27—Published
2006-05-06—Filed