FIELD: production methods.
SUBSTANCE: method of monazite recycling includes the milling of the monazite, processing during the heating by substance of hydroxide of alkaline metal, generating of the salt of phosphor acid, dilution of the filter cake in the mineral acid with the following abstraction of rare earth elements (REE), thorium and uranium. Processing is done by substance of kalium hydroxide = 1:1.0-1.5 with obtaining the substance of triallyl phosphate kalium and precipitation, containing the hydroxide of thorium, uranium, REE, notopened monocyte and empty land, which is processing by azotic acid, extending the nitrate REE in the substance. It is importuned from the substance the carbonates of REE by kalium carbonate. The rest of cake is processing by the substance of kalium carbonate with translating uranium into the substance and following importuning as dihydroxide dioxuranium and the final processing of the cake by the substance of azotic acid with generating thorium into the substance by importuning of thorium by the substance of kalium carbonate. The mother water from the importuning of REE, thorium and uranium and three kalium phosphate is distained to the producing of manuring. The substance of three kalium phosphate and hydroxide kalium is vapored , and it is separated crystal three kalium phosphate, and hydroxide kalium is distained to the head of process. The rest after processing by azotic acid not opened monocyte is distained to the head of process.
EFFECT: simplifying of the process and more effective using of all components of monoyte.
6 cl, 1 ex
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Authors
Dates
2008-05-10—Published
2005-05-17—Filed