FIELD: organic synthesis.
SUBSTANCE: invention pertains to obtaining branched alkanes with general formula CnH2n+2, where n = 4-10. CCI4 is gradually added to a mixture of hexane, triethylaluminium - Et3Al and a catalyst - PdCl2, in an argon atmosphere at atmospheric pressure and temperature of 10-60°C for a period of 0.5-2 hours. The molar ratio of hexane: Et3Al : CCl4 : PdCl2 is 75:10:20:0.1.
EFFECT: obtaining of a mixture of branched alkanes with high output.
1 tbl, 1 ex
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Authors
Dates
2008-06-27—Published
2006-01-31—Filed