METHOD OF OBTAINING HYDROCARBONS C-C Russian patent published in 2008 - IPC C07C2/84 C07C11/02 C07C9/02 B01J21/06 B01J23/06 B01J23/04 B01J23/34 B01J23/30 

FIELD: chemistry.

SUBSTANCE: method of obtaining hydrocarbons C₂-C₃ by high-temperature catalytic oxidizing conversion of methane lies in supply to reactor, into which catalyst is placed, and whose free volume is filled with inert filling, of initial gas mixture, which contains mixture of methane and molecular oxygen, at rate 50000-70000 m/g/h, catalyst includes into its composition ions of alkali metal, manganese, tungsten and silicon oxide with molar ratio M:W:Mn:Si, where M-Na or K or Rb or Cs, equal 1.8-2.2:1:1.9-2.3:89-92, and is characterised by presence in it of tungsten in oxidation degree W⁶⁺, manganese oxidation degrees Mn⁷⁺, Mn⁶⁺, Mn³⁺, catalyst being obtained by thermal processing at 200°C and further incineration at temperature 795-799°C of initial solid powder-like mixture, consisting of salts and/or oxides of tungsten, manganese, alkali metal and SiO₂, taken in said mole ratio in terms per mole of tungsten, manganese, alkali metal and silicon atoms.

EFFECT: increase of target product output, catalyst productivity, simplification of technology of obtaining target products and reduction of expenditures.

11 cl, 1 tbl, 30 ex