FIELD: chemistry.
SUBSTANCE: described is a method of preparing a catalyst for oxidative condensation of methane to C2+ hydrocarbons, which involves depositing manganese and sodium tungstate on a silicon dioxide support via successive impregnation thereof with aqueous solutions of manganese nitrate and then sodium tungstate, followed by calcination in air at temperature of 800°C, wherein the obtained composition Mn - Na2WO4/SiO2 with total content of manganese of 1-2 wt % and sodium tungstate of 3-5 wt % is mixed with an inert material which actively absorbs microwave energy, based on a metal carbide with weight ratio of components of 2-4:1, respectively. Described is a method for oxidative condensation of methane to C2+ hydrocarbons in the presence of a catalyst obtained using the method described above.
EFFECT: high conversion of methane and high selectivity with respect to C2+ hydrocarbons.
6 cl, 2 tbl, 2 ex
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Authors
Dates
2014-05-10—Published
2013-03-05—Filed