FIELD: nanotechnologies.
SUBSTANCE: invention relates to methods for obtaining platinum metal nanoparticles. The method includes electrochemical dissolution of non-ferrous and platinum metals alloy at controllable value of anode potential from +0.1 to +1.2 V with production of nanoparticles of 1-15 nanometers. At dissolution of nickel-platinum metal alloy with platinum metal content of up to 5 wt % in sulphate-chloride dissolvent, anode potential is set to a value of +0.3 V to produce nanoparticles of the size of 10-15 nanometers and to a value of up to +0.8 V to produce noparticles of the size of 1-7 nanometers. At dissolution of nickel-platinum-palladium-rhodium alloy with platinum content of 2%, palladium of 1.5% and rhodium of 1.5 % from mass of alloy, anode potential is set to a value of +0.8 V to +1.2 V to produce nanoparticles of the size of 1-5 nanometers. At dissolution of copper-platinum metal alloy in sulfuric acid, anode potential is set to a value of +0.6 V to produce nanoparticles of the size of 1.0-4.0 nanometers.
EFFECT: chances to obtain nanoparticles of necessary structure and composition by adjusting anode potential value.
5 cl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR OBTAINING NANOPARTICLES OF PLATINUM METALS - IRON ALLOY | 2007 |
|
RU2344022C2 |
PROCESSING WASTES CONTAINING NONFERROUS AND PLATINUM METALS | 2012 |
|
RU2484154C1 |
METHOD OF PRODUCTION OF PLATINUM METALS NANOPARTICLES | 2006 |
|
RU2333077C1 |
METHOD OF PRODUCTION OF SELECTIVE CONCENTRATES OF NOBLE METALS | 2001 |
|
RU2215801C2 |
ELECTROCATALYST FOR REDUCING OXYGEN, FUEL CELL CONTAINING ELECTROCATALYST AND METHOD OF GENERATING ELECTRICAL ENERGY | 2006 |
|
RU2422947C2 |
METHOD OF ELECTROLYTIC REFINING OF NICKEL | 0 |
|
SU1397541A1 |
METHOD FOR PRODUCTION OF NOBLE METAL-BASED SELECTIVE CONCENTRATES | 2003 |
|
RU2241773C1 |
METHOD OF PROCESSING MATERIALS CONTAINING PLATINUM METALS AND SILVER | 2003 |
|
RU2256711C2 |
FUEL-CELL ANODE BASED ON MOLYBDENUM BRONZES AND PLATINUM AND METHOD OF ITS MANUFACTURING | 2014 |
|
RU2564095C1 |
METHOD FOR ELECTROLYTIC REFINING OF COPPER AND NICKEL FROM COPPER/NICKEL ALLOYS | 2003 |
|
RU2237750C1 |
Authors
Dates
2009-01-20—Published
2007-02-05—Filed