FIELD: chemistry.
SUBSTANCE: invention refers to preventive method of thermopolymerisation inhibitors deactivation accompanying separation of C4-hydrocarbon fractions containing sulphur compounds. Method is implemented through rectification with aqueous acetonitrile as extactant and implies that secondary amine is used as additive preventing polymerisation inhibitor deactivation. Application of this method provides linking and transformation of sulphurous compounds into persistive salts of dithiocarbamic acid.
EFFECT: prevention of catalyst deactivation.
2 cl, 1 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
PROCESS FOR RECOVERY AND PURIFICATION OF DIVINYL | 1968 |
|
SU358927A1 |
METHOD FOR INHIBITING SIDE PROCESSES HAPPENING DURING EXTRACTIVE RECTIFICATION USING ACETONITRILE | 2017 |
|
RU2659074C1 |
METHOD FOR SEPARATION OF C-HYDROCARBON FRACTIONS | 2002 |
|
RU2213721C1 |
1,3-BUTADIENE RECOVERY AND PURIFICATION PROCESS | 2006 |
|
RU2304133C1 |
METHOD OF SEPARATING C4-C5-HYDROCARBON MIXTURE OF DIFFERENT SATURATION DEGREE | 0 |
|
SU802251A1 |
0 |
|
SU303859A1 | |
METHOD OF SEPARATING ALKANE AND ALKENE FRACTIONS | 2008 |
|
RU2379277C1 |
METHOD OF PREPARING CONCENTRATE AND HIGH-OCTANE COMPONENTS | 1998 |
|
RU2132838C1 |
METHOD OF SEPARATING C4 OR C5 HYDROCARBON MIXTURES HAVING DIFFERENT DEGREE OF SATURATION | 0 |
|
SU697491A1 |
METHOD OF EXTRACTION ISOPRENE | 1979 |
|
SU772074A1 |
Authors
Dates
2009-01-20—Published
2007-01-09—Filed