FIELD: organic chemistry, chemical technology. SUBSTANCE: invention relates to methods for separation of mixture of C4-hydrocarbons by extractive rectification in the presence of acetonitrile-base extractant. C4-Hydrocarbon fractions are separated by rectification in the presence of extractant containing acetonitrile, 2-10 wt.-% of water and 1.9-30.0 wt.-% of C1-C4-aliphatic alcohols. Primary or tertiary alcohols or their mixtures are used as aliphatic alcohols. Invention provides high selectivity of separation and reduced loss of alcohols in their recuperation. Invention can be used in industry of synthetic rubber, in part, in separation of cracking butane-butylene fractions. EFFECT: improved separating method. 2 cl, 7 ex
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Authors
Dates
2003-10-10—Published
2002-04-11—Filed