FIELD: chemistry.
SUBSTANCE: invention refers to method for making unsaturated polyketones of individually variable molecular weight and carbonyl group content. Disclosed method for making unsaturated polyketones is ensured by isoprene copolymers oxygenation with nitrous oxide (N2O) with diene and/or vinyl monomers at 150-300°C and nitrous oxide pressure 10 to 100 atm. Besides, oxygenation can be enabled with mixed N2O and solvent gases, such as inert gases, alkans C1-C4 or their mixtures. Offered method results in controlled macromolecule C=C bond breakage rupture in initial polymer.
EFFECT: making unsaturated polyketones of specified molecular weight and carbonyl group content.
9 cl, 18 ex
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Authors
Dates
2009-03-27—Published
2007-08-22—Filed