THERMAL SEPARATION METHOD FOR SEPARATING AT LEAST ONE MASS FLOW, CONCENTRATED WITH ACRYLIC ACID Russian patent published in 2009 - IPC B01D3/14 B01D3/32 C07C51/215 C07C51/25 C07C51/43 C07C51/44 C07C51/42 

FIELD: chemistry.

SUBSTANCE: invention relates to a thermal separation method using fractional condensation of a product-gas mixture, obtained through heterogeneous catalysed partial oxidation of propene and/or propane in gaseous phase to acrylic acid, for separating at least one mass flow, concentrated with acrylic acid, from a product-gas mixture containing acrylic acid, which involves continuous static operation of at least one device for thermal separation, containing at least one effective separation chamber with a fractionation column which has mass-transfer trays as built-in separating elements, in which the product-gas mixture is loaded, containing acrylic acid as at least one mass flow, and from which at least one mass flow containing acrylic acid is unloaded under the condition that, the overall mass flow loaded into the effective separation chamber and obtained from combining separate mass flows loaded into the separating chamber, contains X wt % components distinct from acrylic acid, the mass flow which is unloaded from the effective separation chamber with the largest content of acrylic acid, contains Y wt % components distinct from acrylic acid, ratio X:Y is ≥5, effective separation chamber, except the loading and unloading place, is bordered by a solid phase and contains, besides the mass-exchange trays as built-in separating elements in the fractionation column, at least one circulating heat exchanger, and total volume of the chamber, filled with liquid phase, is ≥1 m³, wherein temperature of the liquid phase is at least partially ≥80°C, when the effective separation chamber is divided into n separate volume elements, wherein the highest and lowest temperature of liquid phase in a separate volume element differ by not more than 2°C, and the volume element in the effective separation chamber is solid, total dwell time t_total.

≤20 h, where A = (T_i-T_o)/10°C, T_o= 100°C, T_i = arithmetic mean value of the highest and lowest temperature of the i^th volume element in the liquid phase in °C, m_si = total mass of acrylic acid in the volume of the liquid phase of the i^th volume element, m_i = total liquid phase mass unloaded from the i^th volume element, and is the sum of all volume elements i, under the condition that, volume elements i with liquid phase mass m_i and as volume elements with a dead zone are also not included in the sum of all volume elements i, as well as volume elements i, which do not contain liquid phase, and total amount of liquid phase contained in volume elements with a dead zone is not more than 5 wt % of the total amount of liquid phase contained in the effective separation chamber.

EFFECT: separation of mass flow concentrated with acrylic acid.

10 cl, 12 dwg, 2 ex, 2 tbl