FIELD: chemistry of organometallic compounds, chemical technology, organic synthesis.
SUBSTANCE: invention relates to a method for synthesis of new organoaluminum compounds. Method involves interaction of phenylallyl acetylene with ethylaluminum dichloride in the presence of metallic magnesium and zirconacene dichloride as a catalyst in argon atmosphere at room temperature in tetrahydrofuran medium for 8-12 h. Synthesized organoaluminum compound can be used as a component of catalytic systems in processes of oligomerization and polymerization of olefins and diene hydrocarbons, and in fine and industrial organic and organometallic synthesis also.
EFFECT: improved method of synthesis.
2 cl, 1 tbl, 9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR PRODUCTION OF 2,6-DIALKOXY-2,4,4a,5,6,7,7a,8-OCTAHYDRO-1,3-DIPHENYLALUMINACYCLOPENTADIENO[3,4-f]ISOALUMINAINDOLES | 2005 |
|
RU2283843C1 |
| METHOD FOR PREPARING N, N, N, N-TETRAALKYL-4a,5,7a,8-TETRAHYDRO-1,3-DIPHENYLALUMINA[3,4-f]ISOALUMINAINDOL-2,6-(4H,7H)-DIAMINES | 2005 |
|
RU2283316C1 |
| METHOD FOR PREPARING 1-CHLORO-3,4-DIALKYL-2,5-BIS-(TRIMETHYLSILYL)-ALUMINACYCLOPENTA-2,4-DIENES | 2005 |
|
RU2295528C1 |
| METHOD OF PRODUCING 10-ALKYL-12-ETHYL-12-ALUMINABICYCLO[7.3.0]DODEC-1( 2 )-ENES | 2008 |
|
RU2375368C2 |
| METHOD OF PRODUCING 9-ETHYL-11-ALKYL-9-ALUMINABICYCLO[6,3,0]UNDEC-1(8)-ENES | 2008 |
|
RU2373214C1 |
| METHOD OF PRODUCING 1-ETHYL-3-ALKYLALUMINIUM CYCLOPENTANES | 2009 |
|
RU2433132C2 |
| METHOD OF OBTAINING 1-CHLORO-3,4-DIALKYL-2,5-BIS[3-(1-ALKINYL)PHENYL]-1H-ALUMINOLS | 2007 |
|
RU2348639C1 |
| METHOD OF PRODUCING 3-ETHYL-3-ALUMINATETRACYCLO[12.2.1.0.0]HEPTADEC-4-ENE | 2008 |
|
RU2375367C2 |
| METHOD OF COMBINED PRODUCTION OF 3-ETHYL-3-ALUMINAPENTACYCLO-[12.5.1.0.0.0]-EICOSA-4,16-DIENE AND 3-ETHYL-3-ALUMINAPENTACYCLO-[12.5.1.0.0.0]-EICOSA-4,17-DIENE | 2008 |
|
RU2375369C2 |
| METHOD FOR PREPARING 1,7,8,9-TETRAALKYL-10-ETHYL-4-OXO-10-ALUMINATRICYCLO[5,2,1,0]-DEC-8-ENE-3,5-DIONES | 2004 |
|
RU2275374C2 |
