FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing new organoaluminium compounds, which can be used as components of catalyst systems in oligomerisation and polymerisation of olefin, diene and acetylene hydrocarbons, as well as in fine organic and organometallic synthesis. A method is described for producing new 3-ethyl-3-aluminatetracyclo[12.2.1.02.13.04.12]heptadec-4-ene (1) by reacting an equimolar mixture of cyclonone-1,2-diene and norbornene with ethylaluminium dichloride in the presence of magnesium (powder) and zirconocene dichloride catalyst in an argon atmosphere at room temperature in tetrahydrofuran for 8 to 12 hours.
EFFECT: proposed method allows for obtaining a new compound with high regioselectivity and high output 75-88%.
1 cl, 1 tbl, 9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF COMBINED PRODUCTION OF 3-ETHYL-3-ALUMINAPENTACYCLO-[12.5.1.0.0.0]-EICOSA-4,16-DIENE AND 3-ETHYL-3-ALUMINAPENTACYCLO-[12.5.1.0.0.0]-EICOSA-4,17-DIENE | 2008 |
|
RU2375369C2 |
| METHOD OF PRODUCING 11-ETHYL-11-ALUMINATETRACYCLO[11.2.1.0.0]HEXADEC-3( 10 )-ENE | 2008 |
|
RU2375366C2 |
| METHOD OF PRODUCING 10-ALKYL-12-ETHYL-12-ALUMINABICYCLO[7.3.0]DODEC-1( 2 )-ENES | 2008 |
|
RU2375368C2 |
| METHOD OF OBTAINING 10-ETHYL-11,12-DIALKYL-10-ALUMINABICYCLO [7,3,0]DODECA-8,11-DIENES | 2007 |
|
RU2348640C1 |
| METHOD FOR COMBINED SYNTHESIS OF 1-ETHYL-2-ALKYLIDENEALUMINACYCLOPENTANES AND 1-ETHYL-2-METHYLENE-3-ALKYLALUMINACYCLOPENTANES | 2009 |
|
RU2423370C2 |
| METHOD OF PRODUCING 9-ETHYL-11-ALKYL-9-ALUMINABICYCLO[6,3,0]UNDEC-1(8)-ENES | 2008 |
|
RU2373214C1 |
| METHOD OF OBTAINING 1-ETHYL-1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]ALUMINACYCLOPENTANE | 2007 |
|
RU2342393C2 |
| METHOD FOR PREPARING 2,6-DIETHYL-5,7-DIPHENYL-1,2,3,3a,4,6,8,8a-OCTAHYDROALUMACYCLOPENTADIENO[3,4-f]-ISOALUMAINDOLE | 2004 |
|
RU2280037C2 |
| METHOD OF PRODUCING 1-ETHYL-3-ALKYLALUMINIUM CYCLOPENTANES | 2009 |
|
RU2433132C2 |
| METHOD OF PRODUCING 11-CHLORO-11-ALUMINA-TRICYCLO [10.7.0.0]NONADECA-9,12-DIENE | 2007 |
|
RU2349595C1 |
