FIELD: chemistry.
SUBSTANCE: proposed invention relates to chemical engineering of highly porous ceramic objects with a cellular structure, which can be used as catalyst carriers, filters, headpieces for mass- and heat exchange processes, high-temperature heat-insulating materials etc. A polyurethane matrix with a cellular structure of arbitrary geometrical shape is saturated with slip, consisting of inert filler - electro-cast corundum or a mixture of electro-cast corundum and silicon carbide, dispersed powder of aluminium oxide with additives of group II and IV metal oxides and polyvinyl alcohol solution. The object is dried, calcined and a block-type ceramic object (α-Al2O3) with effective porosity not less than 70-95% is obtained. The object is saturated with alumina sol γ-Al2O3 at pH=4.0±0.2, further dried and calcined at temperature not below 1550°C. Further, the object is saturated with high-molecular alcohol and undergoes pyrolysis in an inert carrier medium, for example nitrogen, at temperature of 350-550°C, depositing pyrolytic carbon onto the surface of the object. The object has weight content of carbon of up to 10%.
EFFECT: formation of a highly developed surface coating for a cellular ceramic object (microporosity reaches up to 30% and above), increased compression strength up to 2,5 MPa.
3 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF MAKING HIGHLY POROUS CELLULAR CERAMIC ARTICLES | 2011 |
|
RU2475464C2 |
METHOD OF MAKING HIGHLY POROUS CATALYST SUPPORT | 2014 |
|
RU2564672C1 |
METHOD TO PRODUCE CERAMIC HIGH-POROSITY BLOCK-CELL MATERIALS | 2014 |
|
RU2571875C1 |
METHOD OF PRODUCING CERAMIC HIGHLY POROUS BLOCK-CELLULAR MATERIALS | 2015 |
|
RU2580959C1 |
METHOD OF MANUFACTURE OF HIGH-POROUS CELLULAR CERAMIC ARTICLES | 2004 |
|
RU2294317C2 |
COMPOSITION OF CHARGE FOR HIGH-POROSITY CERAMIC MATERIAL WITH LATTICED-CELLULAR STRUCTURE | 2013 |
|
RU2525396C1 |
METHOD OF CATALYST PREPARING FOR HYDROGEN OXIDATION | 2014 |
|
RU2546120C1 |
METHOD FOR OBTAINING CERAMIC BLOCK-CELLULAR FILTERS-SORBENTS FOR TRAPPING GASEOUS RADIOACTIVE CAESIUM | 2014 |
|
RU2569651C1 |
COMPOSITION OF CHARGE FOR HIGH-POROUS CELLULAR- STRUCTURE MATERIAL FOR CATALYST CARRIERS | 2002 |
|
RU2233700C2 |
METHOD OF PRODUCING CERAMIC BLOCK-CELLULAR FILTER-SORBENTS FOR TRAPPING GASEOUS RADIOACTIVE AND HARMFUL SUBSTANCES | 2010 |
|
RU2474558C2 |
Authors
Dates
2009-12-27—Published
2008-04-14—Filed