FIELD: chemistry.
SUBSTANCE: invention relates to production of butyl aldehydes via hydroformylation of propylene in the presence of unmodified cobalt catalyst at high temperature and pressure with incomplete conversion of propylene, separation of unreacted propylene from the reaction products and recycling it into the process. The hydroformylation products are cooled to 45-50°C at pressure of 20-30 MPa. Unreacted propylene is extracted from the said products through after-cooling into volume-gravity action separator with propylene residence time of not less than 4 minutes at pressure of 0.1-0.2 MPa, with subsequent extraction of unreacted propylene from the gaseous phase of the separation products through compression, cooling and condensation.
EFFECT: method reduces propylene consumption, increases reactor output, simplifies and reduces cost of process engineering.
3 cl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR INTRODUCTION AND RECLAMATION OF COBALT DURING HYDROFORMYLATION OF PROPYLENE | 2009 |
|
RU2424224C2 |
PROPIONATES, N-PROPANOL AND PROPIONIC ACID PRODUCTION PLANT | 2023 |
|
RU2815838C1 |
PROCESS FOR PREPARING ALDEHYDES AND ALCOHOLS | 0 |
|
SU1097593A1 |
BUTYL ALCOHOLS PRODUCTION PROCESS | 2004 |
|
RU2259345C1 |
METHOD OF DECOBALTIZATION OF PRODUCTS OF HYDRAULIC FORMYLATION OF OLEFINS | 0 |
|
SU1735257A1 |
PROCESS FOR HYDROFORMYLATING OLEFINS | 0 |
|
SU994461A1 |
METHOD FOR COBALT REGENERATION OF COBALT SLUDGE | 2007 |
|
RU2363539C2 |
METHOD FOR OBTAINING BUTYL ALDEHYDES | 0 |
|
SU1657487A1 |
METHOD FOR SEPARATING PRODUCTS OF PROPYLENE HYDROFORMYLATION | 2004 |
|
RU2254323C1 |
METHOD FOR PREPARING BUTYRIC ALDEHYDES CONCENTRATE | 2004 |
|
RU2258059C1 |
Authors
Dates
2010-06-27—Published
2008-12-19—Filed