FIELD: chemistry.
SUBSTANCE: invention discloses introduction of cobalt in form of a cobalt salt solution into a process for hydroformylation of propylene performed in the presence of a cobalt catalyst, where the said cobalt salt solution is specifically cobalt butyrate dissolved in a high-boiling azeotropic mixture of dimethyl acetamide (DMA) and dimethyl formamide (DMF) in butyric acid. Regeneration of a catalyst which is a mixture of cobalt butyrate and the azeotropic mixture of DMA and DMF with butyric acid is performed by treating the still residue after distillation of the end products with water, followed by stripping off the obtained aqueous extract and returning the stripped off residue to the hydroformylation step.
EFFECT: simple hydroformylation process.
2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR COBALT REGENERATION OF COBALT SLUDGE | 2007 |
|
RU2363539C2 |
PROCESS FOR ISOLATING AND RECOVERING COBALT FROM PRODUCTS OF HYDROFORMYLATION OF PROPYLENE | 0 |
|
SU992505A1 |
METHOD OF PREPARING HYDROFORMYLATION CATALYSTS | 1998 |
|
RU2131771C1 |
METHOD FOR SEPARATING PRODUCTS OF PROPYLENE HYDROFORMYLATION | 2004 |
|
RU2254323C1 |
METHOD OF PRODUCING BUTYL ALDEHYDES IN PRESENCE OF UNMODIFIED COBALT CATALYST | 2008 |
|
RU2393145C1 |
PROPIONATES, N-PROPANOL AND PROPIONIC ACID PRODUCTION PLANT | 2023 |
|
RU2815838C1 |
PROCESS FOR HYDROFORMYLATING OLEFINS | 0 |
|
SU994461A1 |
METHOD OF DECOBALTIZATION OF PRODUCTS OF HYDRAULIC FORMYLATION OF OLEFINS | 0 |
|
SU1735257A1 |
METHOD FOR OBTAINING BUTYL ALDEHYDES | 0 |
|
SU1657487A1 |
0 |
|
SU245759A1 |
Authors
Dates
2011-07-20—Published
2009-10-01—Filed