FIELD: chemistry.
SUBSTANCE: invention relates to production of chromium-containing catalyst systems and use thereof in synthesis of hydrocarbons, specifically an olefin oligomerisation method. Described is a method of producing a catalyst system for trimerisation or oligomerisation of olefins, involving a step for mixing a chromium source, a nitrogen-containing ligand and alkyl aluminium in a common solvent in which alkyl aluminium is exposed to microwave radiation when producing the catalyst system. The invention also describes a method for trimerisation or oligomerisation of an olefin compound containing 2-30 carbon atoms per molecule and at least one terminal olefin double bond, involving a trimerisation or oligomerisation step in the presence of the catalyst system obtained using the method described above.
EFFECT: high selectivity of the oliefin oligomerisation and trimerisation reactions, high activity of the catalyst system.
18 cl, 20 ex, 4 tbl
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Authors
Dates
2011-02-20—Published
2009-07-13—Filed