FIELD: chemistry.
SUBSTANCE: catalyst system component is obtained via mechanical activation of a solid mixture with the ratio of 2-ethyl hexanoate of group I metal:CrCl3>1:1 and heating the activated mixture to obtain the desired product. The ethylene oligomerisation catalyst system contains an organoaluminium compound of general formula AlR3, a complexing agent, a modifier, a solvent and a chromium-containing component obtained using the disclosed method. The ethylene oligomerisation method is carried out in the medium of a hydrocarbon solvent at temperature of 40-95°C and ethylene pressure of 1-5 MPa in the presence of said catalyst system.
EFFECT: simple method of producing a component of catalyst systems for oligomerising olefins, high output of the product when oligomerising ethylene to hexene-1, high selectivity of the process and purity of hexene-1, low probability of secondary reactions.
4 cl, 1 tbl, 16 ex
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Authors
Dates
2015-06-20—Published
2013-12-20—Filed