FIELD: chemistry.
SUBSTANCE: invention relates to a method of starting the process, in stationary state, for producing usually gaseous, usually liquid and optionally usually solid hydrocarbons from synthetic gas, where the said process is a Fischer-Tropsch process involving the following steps: (i) providing an activated catalyst in fixed bed reactor pipes, where the said catalyst is suitable for converting synthetic gas to usually gaseous, usually liquid and optionally usually solid hydrocarbons; (ii) bringing the activated catalyst into contact with a liquid in order to obtain a wet activated catalyst; (iii) bringing the wet activated catalyst into contact with synthetic gas and catalytic conversion of the synthetic gas by carrying out a Fischer-Tropsch reaction at high temperature and pressure to obtain usually gaseous, usually liquid and optionally usually solid hydrocarbons, where the liquid at step (ii) is a hydrocarbon or a mixture of hydrocarbons and is brought into contact with the catalyst at temperature lower than the boiling point of the liquid and pressure between 1 and 50 bar (abs.) (0.1-5 MPa).
EFFECT: use of the method enables to lower catalyst activity, thus preventing excess conversion of synthetic gas when initially brought into contact with the catalyst.
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Authors
Dates
2011-03-20—Published
2006-12-06—Filed