FIELD: textile, paper.
SUBSTANCE: method of filler treatment includes formation of a mixture of an aqueous suspension of filler and aqueous anion latex. The latter is a dispersion of acrylic polymer with vitrification temperature (T v) from - 3 to 50°C. This mix is mixed with water at the temperature that is higher than T v of latex, at the same time the specified water has temperature of 40-98°C. The specified suspension of the filler comprises a solid disperse filler selected from the group containing kaolin clay, ground calcium carbonate, deposited calcium carbonate, deposited calcium sulfate, talc and mix of two or more of them. The specified acrylic polymer is selected from the group containing copolymers n-butylacrylate-acrylonitrile-sterol and copolymers n-butylacrylate-sterol. The aqueous composition of the filler contains the solid dispersed filler specified above with solid particles of anion latex polymer specified above and adsorbed on them, in aqueous carrier. The treated filler contains the solid dispersed filler specified above with solid particles of anion latex polymer specified above and adsorbed on them. The pulp charge contains pulp fibres and the solid dispersed filler specified above with solid particles of anion latex polymer specified above and adsorbed on it, in aqueous carrier. Method to make paper from the above specified pulp charge containing pulp fibres. The paper product made of pulp fibres and solid disperse filler, where the specified filler has solid particles of anion latex polymer specified above absorbed on it, with size of solid polymer particles of 30-200 nm and in amount of 1-100 kg of latex per 1 t of filler relative to dry mass of solid substances of latex and filler, and the specified filler has average size of particles of 0.1-30 mcm.
EFFECT: improved retention of the filler, continuous execution of the filler treatment method to improve fixation of anion latex on the filler for a short period of time due to irreversible fixation of anion latexes on particles of the filler and time stability of aggregated filler suspension, latex-treated deposited calcium carbonate is more acid-resistant, and when used to make paper from wood mass under neutral conditions less acid is required to control pH.
21 cl, 14 dwg, 8 ex
Authors
Dates
2011-04-10—Published
2008-06-04—Filed