FIELD: chemical industry.
SUBSTANCE: present invention relates to a group of inventions: a method for producing an aqueous composition, an aqueous composition for optical brightening of a cellulose substrate, the use of an aqueous composition, a coating composition, a method for optically brightening a cellulose substrate, and a cellulose substrate. The method for obtaining an aqueous composition includes emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of at least one water-soluble diaminostilbene-disulfone optical brightener of formula (1):
This method includes the steps: a) preparing an aqueous solution containing or consisting of at least one water-soluble diaminostilbene-disulfone optical brightener of formula (1) and optionally at least one dispersing agent; b) preparing a homogeneous pre-dispersion, the pre-dispersion containing or consisting of at least one ethylenically unsaturated monomer, water and at least one dispersing agent; c) preparing an aqueous solution containing or consisting of a water-soluble azo compound of formula (2) and/or formula (3); d) adding the pre-dispersion obtained in step (b) and the aqueous solution obtained in step (c) simultaneously to the aqueous solution obtained in step (a). The aqueous composition is used to optically brighten a cellulose substrate. The coating composition contains this aqueous composition. A method for optically brightening a cellulose substrate includes: applying a given aqueous composition or coating composition to a cellulose substrate and drying the cellulose substrate. A cellulose substrate treated with a given aqueous or coating composition.
EFFECT: development of water-based latex binders that are easily produced in the form of an emulsion, resistant to washout, capable of providing a higher threshold of whiteness without the use of carriers, toxicologically safe and economical to use.
17 cl, 2 tbl, 7 ex
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Authors
Dates
2023-07-04—Published
2019-09-13—Filed