FIELD: chemistry.
SUBSTANCE: described is use of a catalyst based on crystalline aluminium silicates, which is characterised by molar ratio SiO2/Al2O3 between 20 and 200 and modified with (i) 0.1-10 wt % easily oxidisable metal (in terms of the corresponding metal oxide) and 0.05-5 wt % cerium in terms of Ce2O3, where the easily oxidisable metal used is iron (Fe) in terms of Fe2O3, or (ii) 0.05-5 wt % cerium in terms of Ce2O3, in order to convert oxygen-containing compounds to lower olefins. Described also is a method for catalytic production of lower olefins from oxygen-containing compounds using the catalyst described above as educts with high concentration of water vapour, provided that the molar ratio of water to the oxygen-containing compound in the reaction is between 0.5 and 10.
EFFECT: use of catalysts to convert oxygen-containing compounds to lower olefins.
13 cl, 1 dwg, 2 ex
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Authors
Dates
2011-06-27—Published
2007-05-31—Filed