FIELD: chemistry.
SUBSTANCE: invention relates to compositions for extreme media used in agriculture, cosmetology and everyday life. The compositions contain a surfactant based on an organosilicon compound of the formula: MM', where M=R1R2R3SiO1/2; M'=R4R5R6SiO1/2; where R1 is selected from a group consisting of a branched monovalent hydrocarbon radical containing 3-6 carbon atoms, and R7, where R7 has the formula: R8R9R10SiR12, R8, R9 and R10 are each independently selected from monovalent hydrocarbon radicals containing 1-6 carbon atoms and monovalent aryl or alkylaryl hydrocarbon radicals containing 6-13 carbon atoms, and R12 is a divalent hydrocarbon radical containing 1-3 carbon atoms, R2 and R3 are each independently selected from a group of monovalent hydrocarbon radicals containing 1-6 carbon atoms or R1, with R4 in form of alkyl polyalkylene oxide of general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14, where R13 is a divalent straight or branched hydrocarbon radical, having the structure: -CH2-CH(R15)(R16)dO-, where R15 is H or methyl; R16 is a divalent alkyl radical with 1-6 carbon atoms, where the subscrip d is equal to 0 or 1; R14 is selected from a group consisting of H, monovalent hydrocarbon radicals with 1-6 carbon atoms and acetyl, where subscripts a, b and c are equal to zero or positive numbers and satisfy the following relationships: 2≤a+b+c ≤20 for a≥2, and R5 and R6 are each independently selected from a group of monovalent hydrocarbon radicals containing 1-6 carbon atoms or R4. The compositions have hydrolysis resistance in a wide pH range.
EFFECT: invention increases hydrolytic stability of the compositions.
65 cl, 21 tbl, 13 ex
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Authors
Dates
2011-12-20—Published
2006-12-11—Filed