FIELD: chemistry.
SUBSTANCE: disclosed is a method which involves heterofunctional polycondensation of polyphenylsilsesquioxane and polydiorganosiloxane of formula (I), where n=100-640, in an organic solvent medium in the presence of diethylhydroxyl amine at temperature 110-120°C and weight ratio of polyphenylsilsesquioxane to polydiorganosiloxane ranging from 10:90 to 50:50.
EFFECT: method enables to obtain block copolymers, cold curing vulcanisates of which, along with good physical and mechanical properties, have good oil-and-petrol resistance.
1 cl, 1 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
SILOXANE BLOCK-COPOLYMERS CONTAINING METHYL (HEXAFLUOROALKYL) SILOXANE LINKS | 2014 |
|
RU2563253C1 |
METHOD OF OBTAINING POLYORGANOSILSESQUIOXANE-POLYDIORGANOSILOXANE BLOCK COPOLYMERS | 2014 |
|
RU2571866C1 |
METHOD OF PREPARING POLYPHENYLSESQUIOXANOPOLYDIORGANYLSILOXANE BLOCK COPOLYMERS | 1997 |
|
RU2135529C1 |
METHOD FOR PRODUCING SILOXANE BLOCK COPOLYMERS | 2016 |
|
RU2631111C1 |
METHOD OF PREPARING POLYPHENYLSEQUIOXANE POLYDIORGANOSILOXANE BLOCK COPOLYMERS | 1998 |
|
RU2142478C1 |
COMPOSITION BASED ON A LINEAR-LADDER SILOXANE BLOCK-COPOLYMER FOR PRODUCING PROTECTIVE COATINGS | 2020 |
|
RU2727373C1 |
SILICON-ORGANIC COMPOSITION FOR ELECTRONIC EQUIPMENT PROTECTION | 2016 |
|
RU2631820C1 |
POLYDIMETHYLMETHYL(HEXAFLUOROALKYL)SILOXANES FOR HEAT-, OIL- AND PETROL-RESISTANT MATERIALS | 2013 |
|
RU2527968C1 |
SILICON COMPOSITE MATERIAL | 2008 |
|
RU2377264C1 |
LOW-MOLECULAR TERNARY COPOLYMERS OF VINYLIDENE FLUORIDE AND MONOMER CONTAINING FLUOROSULPHATE GROUP | 2010 |
|
RU2432366C1 |
Authors
Dates
2012-01-10—Published
2010-06-25—Filed