FIELD: chemistry.
SUBSTANCE: present invention relates to a method of producing alkoxy-polyoxyalkylene(meth)acrylates. Described is a method of producing alkoxy-polyoxyalkylene(meth)acrylate, in which: a) at least one metal compound of formula MetOR10 is taken, where Met denotes lithium, sodium, potassium, rubidium or caesium, and where R10 denotes hydrogen or a straight or branched alkyl residue, b) at least one alcohol R12OH is added, where R12 denotes a straight alkyl residue, with 1-18 carbon atoms or 2-(2-(2-methoxyethoxy)ethoxy)ethyl, where the molar mass of R12 is less than that of alkoxy-polyoxyalkylenes, c) at least one alkylene oxide of formula (VI) is added and reacts with the metal compound of formula MetOR10, where residues R11 denote, in each case independently from each other, hydrogen or a straight alkyl residue, and d) (meth)acrylic acid anhydride is directly added and reacts with the product from step c) in the presence of a stabiliser or a mixture of stabilisers.
EFFECT: simple and improved method of producing alkoxy-polyoxyalkylene(meth)acrylates.
9 cl, 16 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING CARBOXYLIC ACID DERIVATIVES | 2007 |
|
RU2448949C2 |
MACROMONOMERS CONTAINING POLYISOBUTENE GROUPS AND THEIR HOMO- AND COPOLYMERS | 2017 |
|
RU2745788C2 |
FUNCTIONALISED (METH)AKRYLATE MONOMER, POLYMER, COATING PREPARATION, METHOD OF OBTAINING AND METHOD OF CROSS-LINKING | 2009 |
|
RU2523549C9 |
PHOTOPOLYMER FORMULATIONS WITH ADJUSTABLE MECHANICAL MODULUS GUV | 2010 |
|
RU2542975C9 |
METHOD FOR OBTAINING THE MODIFIED EPOXIES OF (METH) ACRYLATE RESINS AND THEIR APPLICATION | 2013 |
|
RU2648042C2 |
NEUTRALISED POLYMERS CONTAINING ACID GROUPS AND APPLICATION THEREOF | 2007 |
|
RU2432153C9 |
METHOD OF MAKING HOLOGRAPHIC FILM | 2010 |
|
RU2542984C2 |
REACTION RESIN COMPOSITION AND USE THEREOF | 2014 |
|
RU2667544C2 |
RESIN MIXTURE BASED ON EPOXY(METH)ACRYLATE RESIN AND USE THEREOF | 2013 |
|
RU2649437C2 |
ADHESIVE BASED ON GRAFT COPOLYMERS OF POLYESTERS AND POLY(METH)ACRYLATE | 2008 |
|
RU2479613C2 |
Authors
Dates
2012-01-27—Published
2007-01-30—Filed