FIELD: chemistry.
SUBSTANCE: copolymers contain the following, in terms of total weight of the copolymer: a) 40-97 wt %, preferably 45-90 wt % perfluoroalkyl ethyl methacrylate, b) 1-50 wt %, preferably 5-30 wt % C12-C22 alkyl(meth)acrylate and c) 0.5-10 wt %, preferably 1-5 wt % of one or more thermally cross-linked or isocyanate-reaction monomers, and d) 1.5-50 wt %, preferably 4-30 wt % vinyl chloride and/or vinylidene chloride. The mixture of perfluoroalkyl ethyl methacrylates has the formula RfCH2CH2OCOC(CH3)=CH2, where RF is a perfluoroalkyl chain and contains 1-70 wt % 4 or less fluorinated carbon atoms and 30-99 wt % 6 fluorinated carbon atoms.
EFFECT: obtaining copolymers and aqueous mixtures of copolymers for finishing fibrous substrates.
7 cl, 7 ex, 3 tbl
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