METHOD OF PRODUCING (METH)ACRYLATES OF TETRA- OR MORE POLYBASIC ALCOHOLS Russian patent published in 2012 - IPC C07C67/03 C07C69/54 

Abstract RU 2446144 C2

FIELD: chemistry.

SUBSTANCE: invention relates to an improved method of producing high-purity acrylic and methacrylic esters, obtained via reesterification of (meth)acrylic esters of formula I , where R1 is hydrogen or methyl and R2 is an alkyl residue with 1-40 carbon atoms, with alcohols containing four or more esterifiable hydroxyl groups and selected from a group of tetrabasic alcohols of formula II: R'"(OH)n, where n ≥ 4 and R"' denotes, if necessary, a branched aliphatic or aromatic radical wiht 4-40 carbon atoms, in the presence of lithium amide as a reesterification catalyst, taken in amount of 0.01-10 wt % per total weight of the reaction mixture.

EFFECT: improved method of producing high-purity acrylic and methacrylic esters.

4 cl, 3 ex

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RU 2 446 144 C2

Authors

Shmitt Bardo

Knebel' Joakhim

Grehff Gjunter

Dates

2012-03-27Published

2006-08-16Filed