FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 1,2-alkylene carbonate and versions of the method of producing 1,2-alkylene diol and dialkylcarbonate using the obtained 1,2-alkylene carbonate. The method producing 1,2-alkylene carbonate involves (i) contacting carbon dioxide, 1,2-alkylene oxide and a carbonisation catalyst in a reactor to form a crude stream which flows from the reactor and contains carbon dioxide, light components, 1,2-alkylene carbonate and the catalyst; (ii) separating carbon dioxide and light components from the crude stream flowing from the reactor to form a lower stream containing 1,2-alkylene carbonate and catalyst; (iii) distilling the lower stream formed at step (ii) to obtain a first distillation upper stream containing 1,2-alkylene carbonate and light components and a first distillation lower stream containing a catalyst, and recycling at least a portion of the first distillation lower stream into the reactor and (iv) distilling the first distillation upper stream to form a second distillation upper stream containing light components and a second distillation lower stream containing 1,2-alkylene carbonate, and recycling at least a portion of the second distillation upper stream into the reactor.
EFFECT: method enables to obtain 1,2-alkylene carbonate which does not contain or almost does not contain impurities.
16 cl, 2 ex 1 tbl, 2 dwg
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Authors
Dates
2012-10-20—Published
2008-04-17—Filed